name
Rusnak Gleb Vitalyevich
Scholastic degree
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Academic rank
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Honorary rank
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Organization, job position
• Krasnodar Research Institute of Agricultural Products Storage and Processing
старший научный сотрудник отдела контроля качества и стандартизации
Research interests
Разработка экологически безопасных экспресс-способов оценки качества и идентификации растительного сырья и продуктов его переработки, в том числе с применением метода ядерно-магнитной релаксации
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Articles count: 3
Сформировать список работ, опубликованных в Научном журнале КубГАУ
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DEVELOPMENT OF ECOLOGICALLY SAFE EXPRESS-METHOD FOR QUALITY EVALUATION OF SOYBEAN LECITHINS
Description
The article presents data, on the basis of which we have concluded that the oil and phospholipids contained in soy lecithins, the degree of unsaturation of fatty acids differ significantly from oil and phospholipids contained in sunflower lecithins, with differences in the degree of unsaturation of fatty acids of oil and phospholipids contained in sunflower and soy lecithins, leads to differences in the content of resonating protons, and, consequently, the level of amplitude values of NMR signals of protons of the investigated lecithins. It is established that the values of the amplitudes of the NMR signals of protons of each of the four components of sunflower lecithins differ from the values of the amplitudes of the NMR signals of protons the component of soy lecithins, which confirms the differences in the composition and content of fatty acids lecithins studied. Considering quantitative characteristic of mass fraction of substances insoluble in acetone, i.e. phospholipids, is the sum of the amplitudes of the NMR signals of protons of the third (A3) and fourth (A4) component, was built the graphical dependence of the mass fraction of substances insoluble in acetone, from the value of (A3+A4)/ASIS, % which is described by the equation (correlation coefficient R2 =0,9911) of the following form: y=0,8177x +2.52. Based on these data, we have developed a rapid method of determining the mass fraction of substances insoluble in acetone, soy lecithin, eliminating the use of toxic organic solvents, is environmentally safe, which is protected by RF patent for the invention
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Description
The article provides an overview of Express-methods of quality evaluation and identification of lipidcontaining plant raw materials (oil seeds) and its processed products (oil cakes, oilseed meals, vegetable oils, lecithins) using pulse method of nuclear magnetic resonance. Development of express methods of quality evaluation and identification of lipid-containing plant raw materials and products of its processing is a priority, as these methods are environmentally safe and also allow us to regulate technological conditions of refining processes, are characterized by low error of determination, i.e., high precision, and, in some cases, it is only possible to use because of its non-destructive effects on the analyzed sample. Currently, we can distinguish the following main directions of quality evaluation and identification of lipid-containing plant raw materials and products of its processing on the basis of the pulse method of nuclear magnetic resonance: assessment of quality and identification of oilseeds (sunflower, canola, flax, soybeans); evaluation of quality of products of processing of oil raw materials (cake and meal); the quality evaluation and identification of vegetable oils; assessment of the quality of the lecithins obtained from vegetable oils. The methods of quality evaluation and identification of lipid-containing plant raw materials and its products are patented and have several advantages: short time (5 minutes) spent on the implementation of the single analysis; eliminates the use of toxic chemicals; does not require special training of laboratory personnel; non-destructive character, which is especially important for oilseeds from the point of view of breeding work. On the basis of the conducted survey we can conclude that the pulse method of nuclear magnetic resonance has found wide application for assessment of quality and identification of lipidcontaining plant raw materials and products of its processing, through rapid capabilities, high accuracy and ease of analysis
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Description
In recent decades, Russia has increased the demand for high oleic sunflower oil and, consequently, for the raw material from which it is derived – high oleic sunflower seeds. Currently existing methods of control of mass fraction of oleic acid in the seed oil of sunflower, have significant drawbacks, due to which sharply raises the question of the development of the Express methods of control of mass fraction of oleic acid. The study presents the results of determining the mass fraction of oleic acid in the oil of sunflower seeds, obtained by known methods (GC and ri), and developed a method based on NMR. The developed method of determining the mass fraction of oleic acid in sunflower seed oil has a number of advantages compared with the known: is not destructive (does not require the extraction of oil from seeds), does not require special sample preparation excludes the use of toxic chemicals, the analysis duration is 5 minutes, ensuring high representativeness of the sample, and the simplicity and automation of the analysis process reduces the requirements for qualifications of laboratory personnel. The developed method of determining the mass fraction of oleic acid in the oil of sunflower seeds can be carried out simultaneously with the determination of oil and moisture content of seeds on commercially available analyzers, but I hope it 1006М, which is currently applied at more than 250 companies of oil and fat industry
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