02.00.00 Chemical sciences
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Description
The method of nanoemulsions obtaining with acoustic chemistry method has been considered in the article, the nanoemulsion formula has been found. The researches for emulsion stability and particle sizes determination have been fulfilled. The antioxidant effect of the obtained emulsion and a possibility to use it in meat-vegetable products have been researched
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Description
Correlations between values of the differences of first potentials ionization of atoms and molecules (ΔE) and valency angels α for three coordinated molecules of types ЭХ3 (Э=N, P, As, Sb are carried out; X=F, Cl, Br, I, CH3), and also ЭХ2 (Э=O, S, Se, Te; X = CH3, SiH3, GeH3) are described in this article. It is shown, that the entered value ΔE can serve as additive measure of change of the valency angle α in the basic and raised stances. We have also established that the functional dependences correlate with changes in the of hybridization of orbitals and the R parameters characterizing the interaction of electronic pairs near the central Э atom
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Description
In the article we have optimized reaction conditions of furfurilidenatseton with epichlorohydrin in the presence of a catalyst of tin chloride and held hydrogenation of double bond of 2-methylene -2 - [(2-furyl]-X-1,3 – dioxolan; we have also given the biological activity of some unsaturated furan 1,3- dioxolans
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DEVELOPMENT OF TECHNOLOGY OF WHEY BASED DRINKS, ENRICHED WITH PLANT COMPONENTS
Description
Data of application of researches of vegetative components in reception of drinks from dairy whey of a functional purpose are shown
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ABOUT POLARIZATIONS EFFECTS IN THE RANKS OF ЭХ3 MOLECULES
Description
Correlations between experimental dipoles moments and values of the difference of first potentials ionization of atoms and molecules (ΔE) for three -coordinated molecules of types ЭХ3 (Э=N, P, As, Sb are carried out; X=F, Cl, Br, I ) are described. Exponential functions of dependence μ= f(ΔE) for rows ЭF3 andЭCl3 are received. Within the valence of shell electron pair repulsion theory it is shown, that the molecular dipole moments can be divided to dipol moments of ions of separate atoms, which, naturally changing, are transferred in the ranks of molecules ЭХ3
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SYNTESIS OF 2-R-4-HYDROXYMETHYL-6-METHYLNICOTINATES OF ALKALINE METALS
Description
New 2-R-4-hydroxymethyl-6-methylnikotinates of alkaline metals are synthesized by alkaline hydrolysis of derivatives 6-methyl-1,3-dihydrofuro-[3,4-c]pyridine-3-on
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PLANT GROWTH REGULATORS IN THE SERIES OF NICOTINIC ACID DERIVATIVES
Description
The article shows the information of the use of 2-R-sulfanyl nicotinates of potassium on rice crops. We have found that the compounds described increase yield and improve its quality
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Description
The stability of strongly basic anion-exchange membranes MA-41-2P (JSC "Schekino-Nitrogen", Russia) and AMX (Tokuyama Soda, Japan) under intensive current regimes was investigated in the current study. The process of water molecules dissociation at current densities above the limiting one in 0.01 M sodium chloride solution was studied in detail. The length of the electroconvective instability at the membrane / solution interface at currents exceeding the limiting current was measured by laser interferometry
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Description
In the article the mathematical model of the space charge region in the bipolar membrane is considered. The structure of the space charge region under passing of electric current, and without electric current is discussed. The results of experimental studies of water dissociation in the bipolar membrane in the presence of chromium(III) are discussed
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Description
This publication examines the relationship between the structure of molecules of complexing (descriptors of electronic structure), which are used as inhibitors of hydrogen embrittlement of the steel grade St3, and the content of absorbed hydrogen in model samples-plates made of the above steel. The form of expression of this relationship is the correlation coefficient (CC) by Pearson
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