name
Kaigorodova E. A.
Scholastic degree
•
Academic rank
professor
Honorary rank
—
Organization, job position
• Kuban State Agrarian University
Research interests
Web site url
—
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Current rating (overall rating of articles)
0
TOP5 co-authors
Articles count: 5
Сформировать список работ, опубликованных в Научном журнале КубГАУ
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Description
This article is dedicated to the memory of the staff of teachers, academicians and students of soil science and agricultural chemistry faculty, who have worked and stud-ied in years of its establishment. It has materials from the history of the oldest Kuban State Agrarian University de-partments’: soil science, agricultural chemistry, inorganic and analytical chemistry, organic chemistry
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Description
The present article belongs to the area of organic chemistry, namely, to chemistry of heterocyclic compounds. For the purpose of optimization of a method of synthesis the threecyclic heteroaromatic systems containing a pyridi-ne, thiophen and pyrimidine ring in one molecule, - tetrahydropyridothienopyrimidinon and dihydropyri-dothienopyrimidinon – reaction 3-aminothieno[2,3-b]-pyridine-2-carbokxamides with aromatic aldehydes is studied, some of which contain pharmacolodical groups. Reaction was carried out in the conditions of an acid catalysis – is used p-TsOH. Influence of the nature of solvent (toluene, ethanol, mix ethanol-dimethilform-amide (1:1)) on the course and the direction of reaction are studied. It is established that carrying out reaction in toluene leads to the dihydropyrimidine containing in situation 2 phenyl, 4-bromphenyl deputies. In the presence in a molecule of initial aldehyde of the deputy in orto-situation tetrahydropyrimidine are formed. Use of ethanol mainly leads to formation of a tetrahydro-pyrimidine ring. Boiling of initial substances in mix ethanol-DMF yields the results similar to use of toluene, but time of reaction is reduced twice. The way of receiving the dihydroderivatives short-term boiling of tetrahydropyrimidine is found in mix isopropanol-DMF (a volume ratio of solvents 1:3). Identity of the received substances is proved by method of a thin layer chroma-tography. The structure of the synthesized connections is confirmed with the element analysis. The structure of tertagidropirimidinon and digidropirimidinon is proved with use of data of IK and NMR 1H of the spectral analysis
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PLANT GROWTH REGULATORS IN THE SERIES OF NICOTINIC ACID DERIVATIVES
Description
The article shows the information of the use of 2-R-sulfanyl nicotinates of potassium on rice crops. We have found that the compounds described increase yield and improve its quality
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SYNTESIS OF 2-R-4-HYDROXYMETHYL-6-METHYLNICOTINATES OF ALKALINE METALS
Description
New 2-R-4-hydroxymethyl-6-methylnikotinates of alkaline metals are synthesized by alkaline hydrolysis of derivatives 6-methyl-1,3-dihydrofuro-[3,4-c]pyridine-3-on
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Description
3-Pyrrol-1-ylthieno[3,2-b]pyridin-2-carboxylic acid[(phenyl, 1,3-benzodioxol-5-yl)methylen]-hydrazides were synthesized by the reaction of 3-pirrol-1-ilthieno[2,3-b]pyridine-2-carbohydra-zides with aromatic aldehydes
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