name
Bespalov Alexander Valerievich
Scholastic degree
•
Academic rank
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Honorary rank
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Organization, job position
• Kuban State University
доцент кафедры органической химии и технологий
Research interests
мембранные технологии, композиционные материалы, химия высокомолекулярных соединений
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Articles count: 1
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Description
The present work describes the chemical synthesis of poly-N,N-diallyl pyrrolidinium bromide and polyN,N-diallyl morpholinium bromide - high-molecular compounds containing quaternary nitrogen atoms, which included in two five- and/or six-membered heterocyclic rings. These polymers are perspective modifiers for industrially produced anion-exchange membranes, the use of which should significantly improve the resistance to degradation of the membranes at over-limiting current regimes. The structure of obtained polymers was characterized by FTIR, 1H and 13C NMR spectroscopy. The optimal reaction conditions, which increase the yield of desired products, were defined. It is shown that is preferable to use 1-butanol as a solvent and benzoyl peroxide as an initiator
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