02.00.00 Chemical sciences
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MODELING OF CULTIVATION ON PRODUCTIVITY LACTIC ACID PRODUCER LACTOCOCCUS LACTIS CH5
DescriptionThe equations for evaluation of the stationary state of lactic acid microbiological synthesis have been received. The kinetic dependencies for specific biomass growth rate, consumption of the substrate are given. The particular qualities of growth of homofermentative lactic acid producer Lactococcus lactis CH5 depending on the composition nutrient medium: glucose and yeast autolysate concentration are examined. The influence of the method of cultivation on the productivity and the speed of the lactis acid synthesis are analyzed
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Description
Theoretically and experimentally, we investigated the process of adjusting the pH of natural water of hydrocarbonate class electrodialyzer with bipolar membranes with channel length of 40 cm. We experimentally measured concentration of components, pH of the solutions in alkaline and acid channels of electrodeposition depending on the current density. The article describes a mathematical model for long channels; to scale the mass transfer characteristics of the process there was applied and verified a method of compartmentalization, which gave the possibility to calculate the dependence of the component along the channel length at different velocities of flow of the solution. Numerical calculations were compared with experimental data on electrodialyser of 10 cm and 40 cm length
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RESEARCH OF PHASE-TRANSITIVE MATERIALS BY THE EXPERIMENTAL METHODS
DescriptionThe article is devoted to the application of method of differential-scanning microcalorimetry for research of phase-transitive materials on the base of inorganic and organic substances.
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Description
The article is devoted to research and working out of a method of calculation of the thermodynamic data and phase diagrammes of two-componental alloys of fusible metals with use of the databases, known in the literature
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Description
The article is devoted to the research and working out of calculation method of thermodynamic data and phase diagrams of pentonary alloy materials of low-melt
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Description
Article is devoted to the research and working out of calculation method of thermodynamic data and phase diagrams of ternary alloy materials of low-melt metals with the use of data bases known in literature.
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ANALYSIS OF PHASE PLOTS OF STEARINE-PALMITINE-MIRISTINE FATTY ACIDS TRIPLE SYSTEM
DescriptionThe article is devoted to the research of triple mixtures of fatty acids by means of experimental and calculation methods
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ANALYSIS OF PHASE DIAGRAMS OF DOUBLE SYSTEMS OF FAT ACIDS
DescriptionThe article is devoted to research of binary mixtures of fat acids by means of experimental and calculation methods
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STUDY OF THE INTERACTION OF POLYSTYRENE-AZO-O-PHENOL-AZO-RHODANINE WITH ZINC IONS AND CADMIUM
DescriptionSince the industrial revolution a huge amount of pollutants emitted annually into the water most of which is occupied by toxic metals. These metals widely distributed in the environment and of accumulation of a threat to human health. It is known, that cadmium and zinc at high concentrations have a negative impact on nature. In modern wastewater treatment technology we widely use polymeric sorbents with chelating properties. The use of polymeric chelating sorbents (PCS) usage allows separating individual or group trace elements from large volumes of solutions of complex composition, lowering the limit of detection, eliminating or reducing significantly the impact of macrocomponents which increases the cleaning efficiency. The article presents the results of a study of conditions of interaction of zinc (II) ions and cadmium (II) with PCT - polystyrene-azo-o-phenol-azo-rhodanine. We found the optimal values of the conditions for zinc (II) ions and cadmium (II) sorption. We investigated the effect of interfering of the macro- and micro- water components with the sorption of the ions studied. Maximum desorption of metal ions is achieved by washing the concentrate with 10 ml of 2M hydrochloric acid. The data indicate availability of the investigated sorbent for concentration and separation of zinc (II) ions and cadmium (II)
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RESEARCH IN MICRODEFICIENCY OF POLYMERS (ELASTOMER COMPOSITIONS) UNDER UNIAXIAL DEFORMATION
DescriptionMacrodeficiency of polymeric materials, including the pervasive one, is a consequence of the development of initial microdefects which appear in polymers both due to external factors and during their processing. This article solves the task of identification the interrelation and interdependence of structural microdefects of various polymeric materials, consisting in the estimation of the structural parameters under uniaxial deformation. It is experimentally shown that the process of changing microdefects in the material bulk begins to flow more intensely during deformation of the material, having anisotropic structures in the bulk. Change of the parameters of microdefects is not observed compared to the starting material at small quantities of the deformation. In the area of deformation corresponding to the transition of the material from isotropic to anisotropic state parameters of microdefects do not depend on the degree of deformation of the sample, and abrupt changes of the parameters of microdefects are observed after completing the formation of anisotropic patterns. It is shown experimentally the identity of the parameters of microdefects in the bulk material (rubber-based natural caoutchouc) during deformation with the quantities of local deformations at the edge of the artificially created macrodefects. Under uniaxial deformation more than 280-300% and the growth of the quantities of local deformations come out at the edge of the artificially created macrodefects and normalized linear dimension k and decrease the total number n of microdefects