№ 123(9), November, 2016
Public date: 30.11.2016
Archive of journal: Articles count 141, 382 kb
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01.00.00 Physical-mathematical sciences
DescriptionThere is a 2D mathematical model of ion transport binary salt with the main conjugate effects of concentration polarization in the overlimiting current mode: the bulk charge and the dissociation/ recombination of water, gravity and electroconvection and Joule heating the solution in the form of a boundary value problem for systems of differential equations with partial derivatives in the article. This system is presented in a form convenient for numerical solution. We describe the necessary boundary conditions. This article presents a theoretical study of the interaction of forced, gravitational and electroconvection, the dissociation / recombination of water molecules, and Joule heating of the solution and heat transport through membranes. We have constructed a mathematical model of two-dimensional non-stationary ion transport binary salt in a smooth rectangular channel desalting electrodialysis device using equations Nernst-Planck-Poisson, heat conduction and Navier-Stokes equations and the natural boundary conditions. For numerical solution we use the finite element method, with the splitting of task at each new time layer into three subtasks: electrochemical, thermal conductivity, hydrodynamic. Such approach to the development of numerical methods is the original and can solve arising in modeling boundary-value problems for a nonlinear system of partial differential equations