01.00.00 Physical-mathematical sciences
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01.00.00 Physical-mathematical sciences
DescriptionIn the article we build a mathematical model of elec-tro-diffusion of ions in the diffusion layer of a mem-brane system complicated by the occurrence of the previous slow homogeneous chemical reaction with the condition of electrical neutrality of the solution. We have set a two-point boundary value problem and developed a method to solve it; we have given an algorithm and a numerical method for solving it in Comsol 3.5 environment. The formula for limiting kinetic current was derived. Some of the model’s capabilities to describe the properties of the system are given
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01.00.00 Physical-mathematical sciences
DescriptionThe article presents a mathematical model of the effect on ion transport electro convection salt in non-smooth camera channel desalting electro dialysis apparatus in the presence of forced convection. The basic rules of process of electro convection are revealed
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MATHEMATICAL MODELING OF ELECTROCONVECTION IN THE CAPILLARIES. TRANSIENT BEHAVIOR
01.00.00 Physical-mathematical sciences
DescriptionWe propose a mathematical model of ion transport binary salt in electroosmotic flow in a capillary. The capillary is open on one side and immersed in a vessel of large volume, in which the concentration of the solution is maintained constant, and the other side closed ion exchange membrane. The walls are considered wettable, i.e. the solution adheres to the walls. This means that the mathematical modeling used to rate the condition of sticking. We study the boundary value problem for a coupled system of equations Nernst, Planck, Poisson and Navier-Stokes equations. Used boundary conditions of general form. The mathematical model is based on the general laws of transport and contains no adjustable parameters. Using this model, the basic laws of ion transport salt solution liquid flow, the emergence and development electroconvection, distribution of concentration of salt ions in the capillary with a small change in time, ie, in the initial (transitional) regime. We have identified the presence of ion-exchange membrane surface electroconvective vortices and their influence on the mechanisms of ion transport of salt and fluid movement in different areas of the capillary. A feature of the capillary transport is to the right of the vortex region stagnant areas with a higher concentration of ions
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01.00.00 Physical-mathematical sciences
DescriptionIn 1893, the French mathematician J. Adamar raised the question: given a matrix of fixed order with coefficients not exceeding modulo this value, then what is the maximum modulo value can take the determinant of this matrix? Adamar fully decided this question in the case when the coefficients of the matrix are complex numbers and put forward the corresponding hypothesis in the case when the matrix coefficients are real numbers modulo equal to one. Such matrices satisfying the Hadamard conjecture were called Hadamard matrices, their order is four and it is unknown whether this condition is sufficient for their existence. The article examines a natural generalization of the Hadamard matrices over the field of real numbers, they are there for any order. This paper proposes an algorithm for the construction of generalized Hadamard matrices, and it is illustrated by numerical examples. Also introduces the concept of constants for the natural numbers are computed values of this constant for some natural numbers and shown some applications of Hadamard constants for estimates on the top and bottom of the module of the determinant of this order with arbitrary real coefficients, and these estimates are in some cases better than the known estimates of Hadamard. The results of the article are associated with the results of the con on the value of determinants of matrices with real coefficients, not exceeding modulo units
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01.00.00 Physical-mathematical sciences
DescriptionIn this article, on a small and evident numerical example, methodological aspects of a process engineering of detection of knowledge from the trial-and-error data explicitly are considered, representation of knowledge and its usage for problem solving of forecasting, decision making and data domain examination in system-cognitive analysis (SC-analysis) and its programmatic toolkit - intellectual "Eidos" system are shown
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01.00.00 Physical-mathematical sciences
DescriptionThe new methods for system-cognitive analysis to identify and present graphical visualization of causal functions from the large dimension empirical data and its software tools - «EIDOS» system are discussed.
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01.00.00 Physical-mathematical sciences
DescriptionWe have proposed the method for testing of independence of two alternative variables on the basis of statistics of non-numeric data. The method is aimed at application in problems of statistical quality control. Testing of independence is based on set of small samples, i.e., in the Kolmogorov’s asymptotics, when the number of unknown parameters of the distribution increases in proportion to the data size
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METHOD OF REPLICATIONS AMOUNT CHOICE UNDER CARRYING OUT OF EXPERIMENTAL RESEARCHES
01.00.00 Physical-mathematical sciences
DescriptionMethod of replications amount determination under comparison of two samplings dependently on average values of samplings and their standard deviations is presented in this article. Example of samplings comparison by the criteria of Student has been shown.
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01.00.00 Physical-mathematical sciences
DescriptionForecasting method of flow discharge on the reach of the mountain-flat river channel based on water balance equation and stochastic forecasting model of flood situation in a hydrometric section line of river canal is described. The results of test calculations executed for a reaches of the river Kuban are presented
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A TECHNIQUE FOR COMPUTING OF THE TURBULENT DIFFUSION COEFFICIENT VERTICAL COMPONENT
01.00.00 Physical-mathematical sciences
DescriptionThe technique for computing of the turbulent diffusion coefficient vertical component in the context of a mathematical model of admixture dispersion in the surface layer is proposed